Bluebird Promises: Sequential Asynchronous Execution Of Chained Promises With For-Loops Inside

The greatest challenge with nontrivial quantities of async JavaScript is managing execu‐ tion order through a sequence of steps and handling any errors that come up. Promises handle this downside by providing you with a way to manage callbacks into discrete steps that are easier to read and maintain. And when errors occur they are often handled outside the first application logic with out the necessity for boilerplate checks in each step. A promise is an object that serves as a placeholder for a value. That value is usually the outcome of an async operation similar to an HTTP request or reading a file from disk. When an async perform is known as it could immediately return a promise object. Using that object, you presumably can register callbacks that may run when the operation succeeds or an error occurs. By the end of the chapter you need to be snug working with capabilities that return promises and using prom‐ ises to manage a sequence of asynchronous steps. These variations are largely trivial so it's usually simple to work with totally different implemen‐ tations once you're comfortable utilizing commonplace promises. We talk about API variations and compatibility points with different libraries in Chapter 4. Promises created from jQuery deferreds do not conform to the usual ES6 Promise API or behavior. Some methodology names on jQuery promises differ from the spec; for instance, .fail() is the counterpart to .catch(). A more important distinction is in dealing with errors in the onFulfilled and onRejected callbacks. Standard promises mechanically catch any errors thrown in these callbacks and convert them into rejections. In jQuery promises, these errors bubble up the call stack as uncaught exceptions. Also, jQuery will invoke an onFulfilled or onRejected callback synchronously if settling a promise before the callback is registered. This creates the issues with multiple execution paths described in Chapter 1.

For extra differences between commonplace promises and those jQuery provides, refer to a doc written by Kris Kowal titled Coming from jQuery. Some builders may prefer the type of deferred objects or discover them easier to grasp. However, a more significant case for utilizing a deferred is in a scenario the place you can not resolve the promise within the place it is created. Suppose you are using an online employee to carry out long-running tasks. You can use promises to represent the outcome of the duties. The code that receives the response from the net employee will resolve the promise so it needs entry to the appropriate resolve and reject features. Summary Handling errors in asynchronous code can't be accomplished with conventional try/catch blocks. Fortunately, promises have a catch methodology for dealing with asynchronous errors. Although the strategy is a strong software for dealing with issues that occur deep inside your code, you must use it properly to keep away from silently swallowing errors. In addition to the functionality that the standard Promise API provides, libraries similar to Bluebird supply further error dealing with features. This contains the flexibility to report unhandled rejections and to seize the call stack throughout multiple turns of the occasion loop. Why does using a promise callback appear to truncate the stack when compared to the earlier example? Remember that a promise invokes each callback in a separate flip of the occasion loop. At the start of each flip the stack is empty, so none of the capabilities called in earlier turns seem in the stack when the error occurs. Losing the stack between every callback makes troubleshooting more durable. The problem is not unique to promises; it exists for any asynchronous callbacks.

However, it may be a frequent source of frustration when utilizing promises. To address this drawback within the debugger, the Chrome staff added an possibility to indicate the stack throughout turns of the event loop. Now you can see a stack that's stitched collectively at the factors where asyn‐ chronous calls are made. A dedicated panel for debugging promises in the Chrome developer instruments is also in the works. This is a huge assist and other browsers might offer an analogous characteristic by the point you read this. You may also record errors that occur whereas people are using your software in the wild. When that occurs, you don't have the posh of opening the debugger and searching at the stack. Developers have found clever ways to capture the async call stack utilizing a number of Error objects. This is problematic as a end result of browsers expose the call stack for errors in different ways and it could degrade software performance. You can configure Bluebird to capture and report the stack trace across turns of the event loop by calling Bluebird.longStackTraces(). Keep in mind the impact on performance earlier than enabling this feature within the production model of your software. To deal with errors with asynchronous strategies and callbacks, the error-first callback fashion (which we've seen earlier than, and has also been adopted by Node.js) is the commonest conference. Although this works, but it isn't very composable, and ultimately takes us back to what is called callback hell. Fortunately, Promises permit asynchronous code to use structured error dealing with. The Promises.then method takes in two callbacks, a onFulfilled to deal with when a promise is resolved successfully and a onRejected to deal with if the promise is rejected.

The standard Promise API encapsulates the resolve and reject functions contained in the promise. For instance, in case you have a promise object p, you can not call p.resolve() or p.reject() as a end result of those features aren't hooked up to p. Any code that receives a reference to p can connect callbacks using p.then() or p.catch() however the code cannot management whether or not p gets fulfilled or rejected. By encapsulating the resolve and reject functions contained in the promise you'll have the ability to confi‐ dently expose the promise to different items of code whereas remaining sure the code can not affect the fate of the promise. Without this assure you would want to con‐ sider all code that a promise was uncovered to anytime a promise was resolved or rejec‐ ted in an unexpected means. Using deferreds does not imply you need to expose the resolve and reject methods all over the place. The deferred object also exposes a promise that may be given to any code that should not be calling resolve or reject. The first is a revised version of load Image that returns deferred.promise() and the second is the equivalent function carried out with a regular promise. This example is much like the synchronous and asynchronous callback code in the earlier chapter. You can see that the resolver function passed to the Promise con‐ structor executes instantly followed by the log assertion at the end of the script. Then the event loop turns and the promise that's already resolved invokes the onFulfilled handler. Although the example code is trivial, understanding the execu‐ tion order is a key part of utilizing promises successfully. If you do not feel confident pre‐ dicting the execution order of any of the examples so far, think about reviewing the material in Chapter 1 and this section. One of the largest advantages of using promises is the means in which they allow you to deal with errors. Async error handling with callbacks can shortly muddy a codebase with boil‐ erplate checks in every perform. Fortunately, promises allow you to exchange these repetitive checks with one handler for a sequence of features. The error handling API for promises is basically one perform named catch.

How‐ ever, there are some further things to know when utilizing this perform. For instance, it lets you simulate an asynchronous try/catch/finally sequence. And it's straightforward to unintentionally swallow errors by forgetting to rethrow them inside a catch callback. This chapter guides you through error handling in apply so you presumably can write sturdy code. It consists of examples using the usual Promise API in addition to options the Bluebird promise library provides. Here a consumer object with a profilePromise property and a getProfile methodology is cre‐ ated. The getProfile methodology returns a promise that is resolved with an object con‐ taining the user profile info. Then the script passes the consumer to the navbar and account objects, which display info from the profile. Remember that a promise serves as a placeholder for the outcome of an operation. In this case, the consumer.profilePromise is a placeholder used by the navbar.show() and account.show() features.

These capabilities can be safely called anytime earlier than or after the profile information is on the market. The callbacks they use to print the information to the con‐ sole will only be invoked once the profile is loaded. This removes the necessity for an if statement in either operate to verify whether or not the info is ready. In addition to that simplification, using the promise placeholder has another profit. It removes the need for signaling contained in the getProfile perform to display the user‐ name and profile as quickly as the information is prepared. The promise implicitly provides that logic, fortunately decoupled from the primary points of how or when the data is displayed. Async most certainly at all times returns a promise and as such can easily be mixed with promise capabilities, like Promise.all. Your understanding of stack traces on promises is also old/uninformed. I work on an enterprise grade node app that was began back in node 0.11. Bluebird, which was what one used, offers good stack tracing and improved stack tracing has been obtainable for async await for a few years now. Infact, I don't think I have had to exit of my approach to get a decent stack trace in a few yr or more now.

There are certain paradigms you probably can undertake that retains promise chains clean similar to you'll undertake with callbacks. I can't touch upon if async await was carried out poorly as you are definitely extra knowledgeable there with the RFC you shared. AJAX, WebRTC, and Node.js are a few examples of the place asynchronous APIs are found. Although it's easy to write down a quick perform to handle the results of one HTTP request, additionally it is straightforward to get lost in an unpredictable sea of callbacks as a codebase grows and more folks contribute. That's the place a great approach for dealing with asynchronous code is obtainable in and lots of develop‐ ers are selecting to use Promises of their approach. This is the guide I needed when originally choosing an asynchronous strategy, and it is the results of my expertise using promises in JavaScript applications. It explains their use and internal workings whereas exposing difficulties and missteps. Promises are made up of only a few ideas with a small API. The withBrowser operate incorporates the logic to launch and shut the browser, and the fn perform gets and makes use of the browser occasion. Whenever the argument perform returns, the browser is automatically closed, no additional cleanup logic is required. This construction offers a sublime way to stop non-closed sources hanging round. An attention-grabbing facet of this pattern is that it is among the few instances where there is a difference between return fn() and return await fn() . Usually, it does not matter if an async operate returns a Promise or the results of the Promise. But in this case, without the await the lastly block runs before the fn() name is completed.

A potential problem is when there could be some task is operating within the argument function when it returns. This can occur when it begins an asynchronous task and does not wait for it to complete. In this case, the cleanup logic runs and closes the browser instance that may trigger an error. Promise timeouts Promises in Javascript don't have any idea of time. When you employ await or attach a function with .then() , it will wait until the Promise is either resolved or rejected. This is normally not an issue as most async tasks end within an inexpensive time and their result's needed. But when a client is waiting for a response of, let's say, an HTTP server, it is higher to return early with an error giving the caller a chance to retry somewhat than to wait for a potentially long time. Fortunately, there's a built-in Promise helper function that can be used to add timeout functionality to any Promise-based construct. The loadImageWrapper operate accepts the identical url argument as the unique loadImageNodeStyle perform but does not require a callback. Using promisify cre‐ ates a callback internally and appropriately wires it to a promise. If the callback receives an error the promise is rejected. Otherwise the promise is fulfilled with any extra arguments handed to the callback. Standard promises cannot be fulfilled by more than one value. However, some nodestyle callbacks expect a couple of value when an operation succeeds. In this case you presumably can instruct promisify to meet the promise with an array containing all of the arguments passed to the function besides the error argument, which is not related.

Basic Error Propagation Error propagation and dealing with is a significant side of working with promises. This section introduces the basic ideas whereas all of Chapter 5 is devoted to this matter. When one promise is rejec‐ ted all subsequent promises within the chain are rejected in a domino effect until an onRejected handler is found. In apply, one catch function is used at the end of a sequence (see Example 2-12) to deal with all rejections. This strategy treats the chain as a single unit that the fulfilled or rejected final promise represents. Promise.all - This methodology is often used when there are a number of asynchronous tasks which are depending on each other to complete successfully. Promise.all takes an iterable of promises as an input, and returns a single promise as an output. This returned promise will resolve when all of the input's promises have resolved and non-promises have returned, or if the input iterable contains no promises. It rejects immediately upon any of the input promises rejecting or non-promises throwing an error, and can reject with this first rejection message / error. To simplify issues, the promiseWordAppender perform in itemizing 5-5 always returns a Promise object as resolved with the given word argument. The interesting performance in this instance comes with the chained then() strategies on the test1 reference. Notice that inside the first then() technique a return statement is used, which is a way to invoke the parent method once more. Inside the second then() technique one other return statement is used to name the mother or father method another time. Callbacks are one of the used patterns for handling actions that happen in the future. They are easy yet highly effective constructing blocks of asynchronous programming in JavaScript. Callbacks work because capabilities are first-class residents, and we can use features as argument values once we invoke other functions. We can pass a callback perform to the operation we want to execute. Sometime later our callback will be invoked, which usually has the results of the async operation being handed as an argument.

Pagination When a technique does not return all outcomes for a request and it requires multiple calls to get all items. Pending Promise A Promise state where the asynchronous outcome is not yet available. PostMessage An API to speak cross-context, similar to with IFrames and Web Workers. It is an event-based communication where one finish listens for message occasions and the opposite makes use of the postMessage operate to ship messages. You can use the then callback to deal with when the Promise becomes fulfilled, or use await in an async function. When map is invoked it receives an array whose second factor is an unresolved promise. The other two elements are numbers that are immediately handed to the the square callback. After fulfilling the second promise, its worth is handed to sq.. Once square processes all of the values, an array that is identical to the one that the syn‐ chronous array.map() perform would return resolves the promise returned by map. Since using array.map() or Bluebird.map() on this instance produces the identical end result, it doesn't matter what order the values are passed to the callbacks. That solely works so long as the callback used for map doesn't have any unwanted effects. The map operate is supposed to convert one worth to a different utilizing a callback.

How To Find Pressure Of A Gas Given Temperature And Volume

The physical properties of gases are very simple and identical for all gases. These properties of different gases are evident from the fact that all gases generally obey some simple or common gas formula or relation. Boyle's law, Charles law, Avogadro law, Gay Lussac law, ideal gas law, and Graham's law provide the relation between mass, pressure, volume, temperature, and density of ideal gas molecules for learning chemistry or physics. After knowing these experimental ideal gas laws, a theoretical model-based structure of gases was developed in kinetic theory.

Eventually, these individual laws were combined into a single equation—the ideal gas law—that relates gas quantities for gases and is quite accurate for low pressures and moderate temperatures. We will consider the key developments in individual relationships , then put them together in the ideal gas law. Avogadro's Number, the ideal gas constant, and both Boyle's and Charles' laws combine to describe a theoretical ideal gas in which all particle collisions are absolutely equal. The laws come very close to describing the behavior of most gases, but there are very tiny mathematical deviations due to differences in actual particle size and tiny intermolecular forces in real gases.

Nevertheless, these important laws are often combined into one equation known as the ideal gas law. Using this law, you can find the value of any of the other variables — pressure, volume, number or temperature — if you know the value of the other three. The behavior of gases can be described by several laws based on experimental observations of their properties. The pressure of a given amount of gas is directly proportional to its absolute temperature, provided that the volume does not change (Amontons's law). The volume of a given gas sample is directly proportional to its absolute temperature at constant pressure (Charles's law).

The volume of a given amount of gas is inversely proportional to its pressure when temperature is held constant (Boyle's law). Under the same conditions of temperature and pressure, equal volumes of all gases contain the same number of molecules (Avogadro's law). This is Avogadro's law, which states that under the same temperature and pressure, equal volumes of all gases contain the same number of molecules.

This equation shows that if the quantity of gas increases, the volume of gas increases proportionally. In other words, the number of gas atoms or molecules is independent of their sizes or the molar mass of the gas. The law is named after an Italian scientist Amedeo Avogadro who published his hypothesis about the relationship between the gas volume and its amount in moles in 1811. The standard fixed point of the absolute temperature scale is known as the triple point of water. The significance of this point can be seen in Figure 13, which shows some of the conditions of temperature and pressure under which a fixed quantity of water will exist as a solid , a liquid or a gas . Notice that the graph shows low pressures, around 1% of normal atmospheric pressure.

But you can also see that the melting temperature, at which water makes the transition from solid to liquid, increases slightly as the pressure falls. As a consequence, the two lines meet at a temperature of 0.01 °C when the pressure is 600 Pa. Under these unique conditions water vapour, liquid water and solid ice can all coexist in equilibrium. You can use values for real gases so long as they act like ideal gases. To use the formula for a real gas, it must be at low pressure and low temperature. Increasing pressure or temperature raises the kinetic energy of the gas and forces the molecules to interact.

While the ideal gas law can still offer an approximation under these conditions, it becomes less accurate when molecules are close together and excited. Boyle's law asserts that when the temperature of a fixed quantity of gas is held constant, the product of its pressure and volume is constant. Charles' law asserts that when the pressure of a fixed quantity of gas is held constant, the volume is proportional to the quantity (Tcen + 273° centigrade), where Tcen is the centigrade temperature. This suggests that there exists a lowest possible temperature, usually called absolute zero, at about −273° centigrade.

How Do You Find The Volume Of A Gas Given Temperature Gases whose properties of P, V, and T are accurately described by the ideal gas law are said to exhibit ideal behavior or to approximate the traits of an ideal gas. An ideal gas is a hypothetical construct that may be used along with kinetic molecular theory to effectively explain the gas laws as will be described in a later module of this chapter. Although all the calculations presented in this module assume ideal behavior, this assumption is only reasonable for gases under conditions of relatively low pressure and high temperature. In the final module of this chapter, a modified gas law will be introduced that accounts for the non-ideal behavior observed for many gases at relatively high pressures and low temperatures. First, we must determine the question, which is to calculate the volume of a quantity of gas at a given temperature and pressure.

In a second step, after establishing a basis, we must convert the mass of methane that will be the basis into pound moles. Third, we must convert temperature in degrees Fahrenheit into absolute degrees Rankin and, fourth, convert pressure from psig into psia. Fifth, we must select the appropriate ideal gas constant and use it with a rewritten form of Equation 4.11 to determine the volume of 11.0 lbs of methane gas. Finally, we can substitute the values previously determined into the rewritten equation to calculate the volume. An ideal, or perfect, gas is a hypothetical gas that obeys the gas laws in terms of its pressure, volume, and temperature behavior.

Such a gas would have to be composed of molecules that do not interact with one another. Real gases are not always accurately described by the ideal gas equation. Under ordinary conditions, however, the observed behavior of a real gas is only negligibly different from that predicted for an ideal gas. The compressibility factor is a useful thermodynamic property for modifying the ideal gas law to account for behavior of real gases. It is a measure of how much the thermodynamic properties of a real gas deviate from those expected of an ideal gas. It may be thought of as the ratio of the actual volume of a real gas to the volume predicted by the ideal gas at the same temperature and pressure as the actual volume.

The attraction or repulsion between the individual gas molecules and the container are negligible. Further, for an ideal gas, the molecules are considered to be perfectly elastic and there is no internal energy loss resulting from collision between the molecules. Such ideal gases are said to obey several classical equations such as the Boyle's law, Charles's law and the ideal gas equation or the perfect gas equation. We will first discuss the behavior of ideal gases and then follow it up with the behavior of real gases. But something happens to the validity of this assumption as the gas is compressed.

Imagine for the moment that the atoms or molecules in a gas were all clustered in one corner of a cylinder, as shown in the figure below. At normal pressures, the volume occupied by these particles is a negligibly small fraction of the total volume of the gas. As a result, real gases are not as compressible at high pressures as an ideal gas. The volume of a real gas is therefore larger than expected from the ideal gas equation at high pressures.

This relationship between temperature and pressure is observed for any sample of gas confined to a constant volume. An example of experimental pressure-temperature data is shown for a sample of air under these conditions in . An example of experimental pressure-temperature data is shown for a sample of air under these conditions in Figure 9.11. Careful experiments show that the ideal gas laws are only approximately obeyed by different gases. The ideal gas equation can be used to distinguish between ideal gas and real gas.

The gas which obeys this equation is called ideal gas and which does not obey this equation is called real gas. Van der Waals equation was used to derive the properties of real gases. The ideal gas law formula states that pressure multiplied by volume is equal to moles times the universal gas constant times temperature.

The properties of gases were already being studied and described as early as the seventeenth century. Unlike solids, which have a fixed shape and volume, and liquids, which have a fixed volume but can change shape according to the container, gases assume both the shape and the volume of their container. The volume of space occupied by a sample of gas depends on the number of gas molecules present and the sample's pressure and temperature. The relationship between pressure and temperature of a gas is stated by Gay-Lussac's pressure temperature law. This law states that the pressure of a fixed mass of gas held at a constant volume is directionally proportional to its Kelvin temperature .

Therefore, as the pressure of a particular system goes up, the temperature of that system also goes up, and vice versa. Gas laws describe the behavior of gases with respect to the pressure, volume, temperature, and amount. Gases are one of the states of matter, either compressed very tightly or expanded to fill a large space. There is a useful idealization of gas behaviour which can be formally defined as that in which Boyle's law is exactly true for all temperatures and pressures. A gas which behaves in this way is called an ideal gas and although it is an idealization, real gases approach it under certain conditions.

There are two reasons why it is useful to formulate the equations that an ideal gas would obey. First, these equations are simple and provide a valuable 'first approximation' to the equations that describe real gases. Second, the deviations from ideal gas behaviour that real gases exhibit can give us insight into the microscopic properties of real gases.

Much like the combined gas law, the ideal gas law is also an amalgamation of four different gas laws. Here,Avogadro's law is added and the combined gas law is converted into the ideal gas law. This law relates four different variables which are pressure, volume, no of moles or molecules and temperature. Basically, the ideal gas law gives the relationship between these above four different variables. Constant into the ideal gas equation that was equal to the volume actually occupied by a mole of gas particles. Because the volume of the gas particles depends on the number of moles of gas in the container, the term that is subtracted from the real volume of the gas is equal to the number of moles of gas times b.

While ideal gases are strictly a theoretical conception, real gases can behave ideally under certain conditions. Similarly, high-temperature systems allow for the gas particles to move quickly within the system and exhibit less intermolecular forces with each other. Therefore, for calculation purposes, real gases can be considered "ideal" in either low pressure or high-temperature systems. We have just seen that the volume of a specified amount of a gas at constant pressure is proportional to the absolute temperature. In addition, we saw that the volume of a specified amount gas at a constant temperature is also inversely proportional to its pressure.

We can correctly assume that pressure of a specified amount of gas at a constant volume is proportional to its absolute temperature. Let us also add the fact that the volume at constant pressure and temperature is also proportional to the amount of gas. Similarly, the pressure at constant volume and temperature is proportional to the amount of gas. Thus, these laws and relationships can be combined to give Equation 4.10. The volume and temperature are linearly related for 1 mole of methane gas at a constant pressure of 1 atm. If the temperature is in kelvin, volume and temperature are directly proportional.

Charles's law states that the volume of a given amount of gas is directly proportional to its temperature on the kelvin scale when the pressure is held constant. Plotting the pressure against the absolute temperature gives a straight line which when extrapolated passes through the origin. This shows the pressure of the gas is directly proportional to the absolute temperature of the gas. Doubling the temperature will double the pressure for a fixed mass of gas at constant volume. It also shows that if the gas is cooled to absolute zero then the energy of the molecules is at the lowest energy state and therefore cannot generate any pressure.

So, provided we work at low pressures with a constant–volume gas thermometer, the nature of the working substance is of little relevance. Boyle's law states, at a constant temperature, the volume of a definite mass of a gas is inversely proportional to its pressure. Therefore, the volume of a given quantity of gases, at constant temperature equilibrium with the pressure of gases.

At constant temperature and 1 atm pressure, a cylinder contains 10 ml of methane or hydrogen gas. If the pressure increases to 2 atm then according to Boyle's Law volume decreases to 5 ml. This ideal gas law calculator will help you establish the properties of an ideal gas subject to pressure, temperature, or volume changes.

Read on to learn about the characteristics of an ideal gas, how to use the ideal gas law equation, and the definition of the ideal gas constant. Temperature is sometimes measured with a gas thermometer by observing the change in the volume of the gas as the temperature changes at constant pressure. The hydrogen in a particular hydrogen gas thermometer has a volume of 150.0 cm3 when immersed in a mixture of ice and water (0.00 °C).

When immersed in boiling liquid ammonia, the volume of the hydrogen, at the same pressure, is 131.7 cm3. Find the temperature of boiling ammonia on the kelvin and Celsius scales. The simple and ideal gas laws describe the behavior of pure gaseous substances. Mixtures of gases also behave like ideal gases, provided the different components do not undergo a reaction, or interact in some other way. This concept—that each individual gas in a mixture expands to exert its partial pressure as if the other gas components were not present—was developed by John Dalton in 1801 and is known as Dalton's law of partial pressures.

The volume of space occupied by a sample of gas depends on the number of gas mole-cules present and the sample's pressure and temperature. This is why we have found it necessary to jump backwards and forwards in this module between the basics of thermometry and the properties of gases. Nonetheless, we are now able to define the absolute temperature scale. The behavior of real gases usually agrees with the predictions of the ideal gas equation to within 5% at normal temperatures and pressures.

At low temperatures or high pressures, real gases deviate significantly from ideal gas behavior. The combined gas law is also known as a general gas equation is obtained by combining three gas laws which include Charle's law, Boyle's Law and Gay-Lussac law. The law shows the relationship between temperature, volume and pressure for a fixed quantity of gas.

To first order, pressure ratios are equal to temperature ratios, with thermodynamic temperatures calculated using known virial coefficients. If the constant-volume gas thermometer is to be used in an interpolating gas thermometer mode (as for the ITS-90), the major corrections are due to the nonideality of the gas. The kinetic energy per unit of temperature of one mole of a gas is a constant value, sometimes referred to as the Regnault constant, named after the French chemist Henri Victor Regnault. Regnault studied the thermal properties of matter and discovered that Boyle's law was not perfect.

When the temperature of a substance nears its boiling point, the expansion of the gas particles is not exactly uniform. Decreasing the volume of the container forces the particles to collide more often, so the pressure is increased. As more air goes in, the gas molecules get packed together, reducing their volume. As long as the temperature stays the same, the pressure increases.

According to Charles's law, heating a gas will increase its volume. Also, as noted in the first and second propositions regarding the behavior of gases, gas molecules are highly nonattractive to one another, and therefore, there is a great deal of space between them. The increase in volume makes that space even greater, leading to a significant difference in density between the air in the balloon and the air outside. The major issue with the idea gas law is that it neglects both molecular size and intermolecular attractions, therefore it is most accurate for monatomic gases at high temperatures and low pressures. With lower densities the neglect of molecular size becomes less critical since the average distance between adjacent molecules becomes much larger relative to the size of the molecules themselves.